Publications
Annual Report
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Original Papers
- Analytical TEM Observation of Au Nano-particles on Cerium Oxide
Tomoki AKITA, Mitsutaka OKUMURA, Koji TANAKA, Masanori KOHYAMA, Masatake HARUTA
Catal. Today, 117, 62-68 (2006)
[Web Page]External Link - Special Issue of Catalysis Today Devoted to 5th WCOC
Makoto MISONO, Makoto IMANARI, Masatake HARUTA, Shunichi FUKUZUMI, Takashi TATSUMI, Wataru UEDA
Catal. Today, 117, 1-2 (2006)
[Web Page]External Link - Gas-Phase Radical Generation by Ti Oxide Clusters Supported on Silica: Application to the Direct Epoxidation of Propylene to Propylene Oxide Using Molecular Oxygen as an Oxidant
Naoaki MIMURA, Susumu TSUBOTA, Kazuhisa MURATA, Kyouko BANDO, J. J. BRAVO-SUAREZ, Masatake HARUTA
Catal. Lett, 110, 47-51 (2006)
[Web Page]External Link - Direct Propylene Epoxidation over Modified Ag/CaCO3 Catalysts
Jiquing LU, J. J., BRAVO-SUAREZ, Masatake HARUTA, Ted. S. OYAMA
Appl. Catal. A.: General, 302, 283-295 (2006)
[Web Page]External Link - Trimethylamine as a Gas-Phase Promoter: Highly Efficient Epoxidation of Propylene over Supported Gold Catalysts
Biswajit CHOWDHURY, J. J. BRAVO-SUAREZ, Masakazu DATE, Susumu TSUBOTA, Masatake HARUTA
Angew. Chem. Int. Ed., 45, 412-415 (2006)
[Web Page]External Link - Gold Catalysts: Towards Sustainable Chemistry (Highlight)
T. Ishida, M. Haruta
Angew. Chem. Int. Ed., 46, 7154-7156 (2007)
[Web Page]External Link - New Generation of Gold Catalysts: Nanoporous Foams and Tubes – Is Unsupported Gold Catalytically Active?
M. Haruta
ChemPhysChem, 8, 1911-1913 (2007)
[Web Page]External Link - In situ Measurements under Flow Condition of the CO Oxidation over Supported Gold Nanoparticles
M. Date, H. Imai, S. Tsubota, M. Haruta
Catal. Today, 122, 222-225 (2007)
[Web Page]External Link - Transient Technique for Identification of True Reaction Intermediates: Hydroperoxide Species in Propylene Epoxidation on Gold/Titanosilicate Catalysts by X-ray Absorption Fine Structure Spectroscopy
J. J. Bravo-Suarez, K. K. Bando, J. Lu, M. Haruta, T. Fujitani, S. T. Oyama
J. Phys. Chem. C, 112, 1115-1123 (2008)
[Web Page]External Link - Direct Deposition of Gold Nanoparticles onto Polymer Beads and Glucose Oxidation with H2O2
T. Ishida, K. Kuroda, N. Kinoshita, W. Minagawa, M. Haruta
J. Colloid Interface Sci., 323, 105-111 (2008)
[Web Page]External Link - TEM and STEM Study of the Au Nano-particles Supported on Metal Oxides
T. Akita, K. Tanaka, M. Kohyama, M. Haruta
MRS Symposium Proceedings, 1026-C17, 14 (2008)
[Web Page]External Link - Theoretical Study of H2O and O2 Adsorption on Au Small Clusters
M. Okumura, M. Haruta, Y. Kitagawa, T. Kawakami, K. Yamaguchi
Gold Bull., 40, 40-44 (2007)
[Web Page]External Link - A kinetic study on the low temperature oxidation of CO over Ag-contaminated Au fine powder
Y. Iizuka, T. Miyamae, T. Miura, M. Okumura, M. Date, M. Haruta
J. Catal., 262, 280-286 (2009)
[Web Page]External Link - HAADF-STEM observation of Au nanoparticles on TiO2
T. Akita, K. Tanaka, M. Kohyama, and M. Haruta
Surf. Interface Anal., 40, 1760–1763 (2008)
[Web Page]External Link - Aerobic oxidation of glucose and 1-phenylethanol over gold nanoparticles directly deposited on ion-exchange resins
T. Ishida, S. Okamoto, R. Makiyama, M. Haruta
Appl. Catal. A: Gen., 353, 243-248 (2009)
[Web Page]External Link - Reduction of 4-nitrophenol over Au nanoparticles deposited on PMMA
K. Kuroda, T. Ishida, M. Haruta
J. Mol. Catal. A: Chem., 298, 7-11 (2009)
[Web Page]External Link - Coprecipitated gold-tricobalt tetraoxide catalyst for heterogeneous hydroformylation of olefins
X. Liu, M. Haruta, M. Tokunaga
Chem. Lett, 37(12), 1290-1291 (2008)
[Web Page]External Link - Reactions of gold atoms with nitrous oxide in excess argon: A matrix infrared spectroscopic and theoretical study
L. Jiang, M. Kohyama, M. Haruta, Q. Xu
J. Phys. Chem. A, 112, 13495-13499 (2008)
[Web Page]External Link - Influence of the support and the size of gold clusters on catalytic activity for glucose oxidation
T. Ishida, N. Kinoshita, H. Okatsu, T. Akita, T. Takei, M. Haruta
Angew. Chem. Int. Ed., 47, 9265-9268 (2008)
[Web Page]External Link - Deposition of gold clusters on porous coordination polymers by solid grinding and their catalytic activity in aerobic oxidation of alcohols
T. Ishida, M. Nagaoka, T. Akita, M. Haruta
Chem. Eur. J., 14, 8456-8460 (2008)
[Web Page]External Link - Theoretical investigation of the hetero-junction effect in PVP-stabilized Au13 clusters. The role of PVP in their catalytic activities
M. Okumura, Y. Kitagawa, T. Kitagawa, M. Haruta
Chem. Phys. Lett., 459, 133-136 (2008)
[Web Page]External Link - Low-Temperature Oxidation of CO Catalysed by Co3O4 Nanorods
X. Xie, Y. Li, Z.-Q. Liu, M. Haruta, W. Shen
Nature, 458, 746-749 (2009)
[Web Page]External Link - N-Formylation of Amines via the Aerobic Oxidation of Methanol over Supported Gold Nanoparticles
T. Ishida, M. Haruta
ChemSusChem, 2, 538-541 (2009)
[Web Page]External Link - Pretreatments of Co3O4 at Moderate Temperature for CO oxidation at -80 °C
Y. Yu, T. Takei, H.Ohashi, H. He, X. Zhang, M. Haruta
J. Catal., 267, 121-128 (2009)
[Web Page]External Link - Propene Epoxidation with Dioxygen Catalyzed by Gold Clusters
J. Huang, T. Akita, J. Faye, T. Fujitani, T. Takei, M. Haruta
Angew. Chem. Int. Ed., 48, 7862-7866 (2009) marked as “Hot Paper”
[Web Page]External Link - Deposition of Gold Nanoparticles on Carbons for Aerobic Glucose Oxidation
H. Okatsu, N. Kinoshita, T. Akita, T. Ishida, M. Haruta
Appl. Catal. A: Gen., 369, 8-14 (2009)
[Web Page]External Link - One-pot N-Alkylation of Primary Amines to Secondary Amines by Gold Clusters Supported on Porous Coordination Polymers
T. Ishida, N. Kawakita, T. Akita, M. Haruta
Gold Bull., 42, 267-274 (2009)
[Web Page]External Link - Aerobic Oxidation of Glucose over Gold Nanoparticles Deposited on Cellulose
T. Ishida, H. Watanabe, T. Bebeko, T. Akita, M. Haruta
Appl. Catal. A: Gen., 377, 42-46 (2010)
[Web Page]External Link - Au@ZIF-8: CO Oxidation over Gold Nanoparticles Deposited to Metal-Organic Framework
H.-L. Jiang, B. Liu, T. Akita, M. Haruta, H. Sakurai, Q. Xu
J. Am. Chem. Soc., 131, 11302-11303 (2009)
[Web Page]External Link - Synergy in Catalysis of Bimetallic Au-Ni Nanoparticles Embedded in SiO2 Nanospheres for Hydrolytic Dehydrogenation of Ammonia Borane
H.-L. Jiang, T. Umegaki, T. Akita, X.-B. Zhang, M. Haruta, Q. Xu
Chem. Eur. J., 16, 3132-3137 (2010)
[Web Page]External Link - Hydrogen Dissociation by Gold Clusters
T. Fujitani, I. Nakamura, T. Akita, M. Okumura, and M.Haruta
Angew. Chem. Int. Ed., 48, 9515-9518 (2009)
[Web Page]External Link - Hydroformylation of Olefins by Au/Co3O4 Catalysts
X. Liu, B. Hu, K. Fujimoto, M. Haruta, M. Tokunaga
Appl. Catal. B: Environ., 92, 411-421 (2009)
[Web Page]External Link - One-Pot Synthesis of Indoles and Aniline Derivatives from Nitroarenes under Hydrogenation Condition with Supported Gold Nanoparticles
Y. Yamane, X. Liu, A. Hamasaki, T. Ishida, M. Haruta, T. Yokoyama, M. Tokunaga
Org. Lett., 11, 5162-5165 (2009)
[Web Page]External Link - Gold Clusters Supported on La(OH)3 for CO Oxidation at 193 K
T. Takei, I. Okuda, K. Bando, T. Akita, M. Haruta
Chem. Phys. Lett., 493, 207-211 (2010)
[Web Page]External Link - Gold Clusters Supported on Alkaline Treated TS-1 for Highly Efficient Propene Epoxidation with O2 and H2
J. Huang, T. Takei, T. Akita, H. Ohashi, M. Haruta
Appl. Catal. B Environ., 95, 430-438 (2010)
[Web Page]External Link - Influence of the Preparation Methods for Pt/CeO2 and Au/CeO2 Catalysts in CO Oxidation
S. Shimada, T. Takei, T. Akita, S. Takeda, M. Haruta
Stud. Surf. Sci. Catal., 175, 843-847 (2010)
[Web Page]External Link - Deposition of Gold Clusters onto Porous Coordination Polymers by Solid Grinding
T. Ishida, N. Kawakita, T. Akita, M. Haruta
Stud. Surf. Sci. Catal., 175, 839-842 (2010)
[Web Page]External Link - Aerobic Oxidation of Glucose over Gold Nanoparticles Deposited on Cellulose
T. Ishida, H.Watanabe, T. Bebeko, T. Akita, M. Haruta
Appl. Catal. A: Gen., 377, 42-46 (2010)
[Web Page]External Link - One-Step Seeding Growth of Magnetically Recyclable Au@Co Core-Shell Nanoparticles: Highly Efficient Catalyst for Hydrolytic Dehydrogenation of Ammonia Borane
J.-M. Yan, X.-B. Zhang, T. Akita, M. Haruta, Q. Xu
J. Am. Chem. Soc., 132, 5326-5327 (2010)
[Web Page]External Link - Synthesis of Acetoaldehyde, Acetic Acid, and Others by the Dehydrogenation and Oxidation of Ethanol
T. Takei, N. Iguchi, M. Haruta
Catal. Surv. Asia, 15, 80-88 (2011)
[Web Page]External Link - Propene Epoxidation with O2 and H2:Identification of the Most Active Gold Cluster
J. H. Huang, E. Lima, T. Akita, A. Guzman, C. X. Qi, T. Takei M. Haruta
J. Catal., 278, 8-15 (2011)
[Web Page]External Link - Synergistic Catalysis of Au@Ag Core-Shell Nanoparticles Stabilized on Metal-Organic Framework
H.-L. Jiang, T. Akita, T. Ishida, M. Haruta, Q. Xu
J. Am. Chem. Soc., 133, 1304-1306 (2011)
[Web Page]External Link - Ultrafine Gold Clusters Incorporated into a Metal-Organic Framework
H.-L. Jiang, Q.-P. Lin, T. Akita, B. Liu, H. Ohashi, H. Oji, T. Honma, T. Takei, M. Haruta, Q. Xu
Chem. Eur. J., 17, 78-81 (2011)
[Web Page]External Link - Switching of reactions between hydrogenation and epoxidation of propene over Au/Ti-based oxides in the presence of H2 and O2
Caixia Qi, J. Huang, Shuangquan Bao, Huijuan Su, T. Akita, M.Haruta
J. Catal., 281, 12-20 (2011)
[Web Page]External Link - Support effect in the gas phase oxidation of ethanol over nanoparticulate gold catalysts
T. Takei, N. Iguchi, M. Haruta
New J. Chem., 35(10), 2227-2233 (2011)
[Web Page]External Link - Role of perimeter interfaces in catalysis by gold nanoparticles
M. Haruta
Faraday Discuss., 152, 11-32 (2011)
[Web Page]External Link - Morphology effects of Co3O4 nanocrystals catalyzing CO oxidation in a dry reactant gas stream
Y. Teng, Y. Kusano, M. Azuma, M. Haruta, Y. Shimakawa
Catal. Sci. Technol., 1, 920-922 (2011)
[Web Page]External Link - Systematic Morphology Changes of Gold Nanoparticles Supported on CeO2 during CO Oxidation
T. Uchiyama, H.Yoshida, Y. Kuwauchi, S. Ichikawa, S.Shimada, M. Haruta, S. Takeda
Angew. Chem. Int. Ed., 50, 10157-10160 (2011)
[Web Page]External Link - Temperature-Dependent Change in Shape of Platinum Nanoparticles Supported on CeO2 during Catalytic Reactions
H. Yoshida, K. Matsuura, Y. Kuwauchi, H. Kohno, S. Shimada, M. Haruta, S. Takeda
Appl. Phys. Express, 4, 065001 (2011)
[Web Page]External Link - From this year, all papers by our staff were listed.
- One-Step Synthesis of Magnetically Recyclable Au/Co/Fe Triple-Layered Core-Shell Nanoparticles as Highly Efficient Catalysts for the Hydrolytic Dehydrogenation of Ammonia Borane
K. Aranishi, H.-L. Jiang, T. Akita, M. Haruta, Q. Xu
Nano Res., 4, 1233-1241 (2011)
[Web Page]External Link - Sequential HAADF-STEM observation of structural changes in Au nanoparticles supported on CeO2
T. Akita, S. Tanaka, K. Tanaka, M. Haruta, M. Kohyama
J. Mater. Sci., 46, 4384-4391 (2011)
[Web Page]External Link - Catalytically Highly Active Top Gold Atoms on Palladium Nanocluster
H. Zhang, T. Watanabe, M. Okumura, M. Haruta, N. Toshima
Nature Materials, 11, 49-52 (2012)
[Web Page]External Link - Support effects of metal oxides on gold –catalyzed one-pot N-alkylation of amine with alcohol
T. Ishida, R. Takamura, T.Takashi, T. Akita, M. Haruta
Appl. Catal. A: Gen., 413-414, 261-266 (2012)
[Web Page]External Link - Visualizing Gas Molecules Interacting with Supported Nanoparticulate Catalysts at Reaction Conditions
H. Yoshida, Y. Kuwauchi, J. R. Jinschek, K. Sun, S. Tanaka. M. Kohyama, S.Shimada, M. Haruta, S. Takeda
Science, 335, 317-319 (2012)
[Web Page]External Link - Metal oxide-catalyzed ammoxidation of alcohols to nitriles and promotion effect of gold nanoparticles for one-pot amide synthesis
T. Ishida, H. Watanabe, T. Takei, A. Hamasaki, M. Tokunaga, M. Haruta
Appl. Catal. A: Gen., 425-426, 85-90 (2012)
[Web Page]External Link - Propene epoxidation with oxygen over gold clusters: Role of basic salts and hydroxides of alkalis
J. Huang, T. Takei, H. Ohashi, M. Haruta
Appl. Catal. A: Gen., 435-436, 115-122 (2012)
[Web Page]External Link - Base-free direct oxidation of 1-octanol to octanoic acid and its octyl ester over supported gold catalysts
T. Ishida, Y. Ogihara, H. Ohashi, T. Akita, T. Honma, H. Oji, M. Haruta
ChemSusChem, 5, 2243-2248 (2012)
[Web Page]External Link - Intrinsic catalytic structure of gold nanoparticles supported on TiO2
Y. Kuwauchi, H. Yoshida, T. Akita, M. Haruta, S. Takeda
Angew. Chem. Int. Ed., 51, 7729-7733 (2012)
[Web Page]External Link - Air purification by gold catalysts supported on PET nonwoven fabric
M. Ikegami, T. Matsumoto, Y. Kobayashi, Y. Jikihara, T. Nakayama, H. Ohashi, T. Honma, T. Takei, M. Haruta
Appl. Catal. B: Environ., 134-135, 130-135 (2013)
[Web Page]External Link - Gold nanoparticles assisted formation of cobalt species for intermolecular hydroaminomethylation and intramolecular cyclocarbonylation of olefins
X. Liu, A. Hamasaki, Y. Yamane, S. Aikawa, T. Ishida, M. Haruta, M. Tokunaga
Catal. Sci. Techol., 3, 3000-3006 (2013)
[Web Page]External Link - Infrared spectroscopic and theoretical studies on the formation of Au2NO- and AunNO (n = 2–5) in solid argon
Y.-L. Teng, M. Kohyama, M. Haruta, Q. Xu
J. Chem. Phys., 130, 134511 (2009)
[Web Page]External Link - In Situ UV-vis and EPR Study on the Formation of Hydroperoxide Species during Direct Gas Phase Propylene Epoxidation over Au/Ti-SiO2 Catalyst
B. Chowdhury, J. J. Bravo-Suárez, N. Mimura, J. Q. Lu, K. K. Bando, S. Tsubota, M. Haruta
J. Phys. Chem. B, 110, 22995-22999 (2006)
[Web Page]External Link - Synergetic combination of an enzyme and gold catalysts for glucose oxidation in neutral aqueous solution
A. Taketoshi, S. Takenouchi, T. Takei, M. Haruta
Appl. Catal. A: Gen., 468, 453-458 (2013)
[Web Page]External Link - Aerobic oxidation of sulfides to sulfoxides catalyzed by gold/manganese oxides
A. Taketoshi, P. Concepción, H. García, A. Corma, M. Haruta
Bull. Chem. Soc. Jpn., 86, 1412-1418 (2013)
[Web Page]External Link - Preparation of microporus polymer-encapsulated Pd nanoparticles and their catalytic performance for hydrogeneration and oxidation
T. Ishida, Y. Onuma, K. Kinjo, A. Hamasaki, H. Ohashi, T. Honma, T. Akita, T. Yokoyama, M. Haruta
Tetrahedron, 70, 6150-6155 (2014)
[Web Page]External Link - With high sensitivity and with wide-dynamic-range localized surface-plasmon resonance sensor for volatile organic compounds
A. Monkawa, T. Nakagawa, H. Sugimori, E. Kazawa, K. Shibamoto, T. Takei, M. Haruta
Sens. Actuators B: Chem., 196, 1-9 (2014)
[Web Page]External Link - Ethanol Oxidation in Water Catalyzed by Gold Nanoparticles Supported on NiO Doped with Cu
T.Takei, J. Suenaga, T. Ishida, M. Haruta
Top. Catal., 58, 295-301 (2015)
[Web Page]External Link - Synthesis and Catalytic Activity of Crown Jewel-Structured (IrPd)/Au Trimetallic Nanoclusters
H. Zhang, L. Lu, K. Kawashima, M. Okumura, M. Haruta, N. Toshima
Adv. Mater., 27, 1383-1388 (2015)
[Web Page]External Link - Interplay of Theoretical Calculations and Experiments for a Study of Catalysis by Gold
M. Okumura, M. Haruta
Catal. Today, 259, 29581–86 (2016) - Deposition of Gold Nanoparticles on Niobium Pentoxide with Different Crystal Structures for Room-Temperature Carbon Monoxide Oxidation
T. Murayama, W. Ueda, M. Haruta
ChemCatChem, 8, 2620-2624 (2016) - Correlation between catalytic activity of supported gold catalysts for carbon monoxide oxidation and metal-oxygen binding energy of the support metal oxides
T. Fujita, M. Horikawa, T. Takei, T. Murayama, M. Haruta,
Chin. J. Catal., 37, 1651–1655 (2016) - Preparation of gold nanoparticles supported on Nb2O5 by deposition precipitation and deposition reduction methods and their catalytic activity for CO oxidation
T. Murayama, M. Haruta
Chin. J. Catal., 37, 1694–1701 (2016) - Efficient Decarbonylation of Furfural to Furan Catalyzed by Three-Atom Palladium Clusters supported on Zirconia
T. Ishida, K. Kume, K. Kinjo, T. Honma, K. Nakada, H. Ohashi, T. Yokoyama, A. Hamasaki, H. Murayama, Y. Izawa, M. Utsunomiya, M. Tokunaga
ChemSusChem, 9, 3441–3447 (2016) - Population and hierarchy of active species in gold iron oxide catalysts for carbon monoxide oxidation
Q. He, S. J. Freakley, J. K. Edwards, A. F. Carley, A. Y. Borisevich, Y. Mineo, M. Haruta, G.J. Hutchings, C. J. Kiely
Nature Commun., 7, 12905 (2016) - Carbon Monoxide Oxidation by Polyoxometalate‐Supported Gold Nanoparticulate Catalysts: Activity, Stability, and Temperature‐Dependent Activation Properties
T. Yoshida, T. Murayama, N. Sakaguchi, M. Okumura, T. Ishida, M. Haruta
Angew. Chem. Int. Ed., 57, 1523–1527 (2018) - Preparation of gold clusters on metal oxides by deposition-precipitation with microwave drying and their catalytic performance for CO and sulfide oxidation
A. Taketoshi, T. Ishida, H. Ohashi, T. Honma, M. Haruta
Chin. J. Catal., 38, 1888–1898 (2017) - Low-temperature CO oxidation over combustion made Fe and Cr doped Co3O4 catalysts: Role of dopant’s nature toward achieving superior catalytic activity and stability
T. Baidya, T. Murayama, P. Bera, O. Safonova, P. Steiger, N. Katiyar, K. Biswas, M. Haruta
J. Phys. Chem. C, 121, 15256–15265 (2017) - Remarkable enhancement of Fe-V-Ox composite metal oxide to gold catalyst for CO oxidation in the simulated amosphere of CO2 laser
Q. Lin, C. Han, H. Su, L. Sun, T. Ishida, T. Honma, X. Sun, Y. Zheng, C. Qi,
RSC Adv, 7, 38780–38783 (2017) - Wacker Oxidation of Terminal Alkenes over ZrO2 Supported Pd Nanoparticles under Acid- and Co-Catalyst-Free Conditions
Z. Zhang, Y. Kumamoto, T. Hashiguchi, T. Mamba, H. Murayama, E. Yamamoto, T. Ishida, T. Honma, M. Tokunaga
ChemSusChem, 10, 3482-3489 (2017) - Chloride-Free and Water-Soluble Au Complexes for Preparation of Supported Small Nanoparticles by Impregnation Method
H. Murayama, T. Hasegwa, Y. Yamamoto, M. Tone, M. Kimura, T. Ishida, T. Honma, M. Okumura, A. Isogai, T. Fujii, M. Tokunaga
J. Catal., 353, 74-80 (2017) - Adsorption Behavior of Au(III) Complex Ion on Nickel Carbonate and Nickel Hydroxide
H. Ando, D. Kawamoto, H. Ohashi, T. Honma, T. Ishida, Y. Okaue, M. Tokunaga, T. Yokoyama
Colloids Surf. A, 537, 383-389 (2018) - Oxide-Supported Palladium and Gold Nanoparticles for Catalytic C-H Transformations
T. Ishida, Z. Zhang, H. Murayama, M. Tokunaga
J. Synth. Org. Chem., Jpn., 75, 1150-1161 (2017) - W-Ti-O Mixed Metal Oxide Catalyzed Dehydrative Cross-etherification of Alcohols
A. Yada, T. Murayama, J. Hirata, T. Nakashima, M. Tamura, Y. Kon, W. Ueda
Chem. Lett., in press, (2018) - Facile Formation of Lactic Acid from a Triose Sugar in Water over Niobium Oxide with a Deformed Orthorhombic Phase
K. Nakajima, J. Hirata, M. Kim, N. K. Gupta, T. Murayama, A. Yoshida, N. Hiyoshi, A. Fukuoka, W. Ueda
ACS Catal., 8, 283-290 (2018) - Synthesis of crystalline microporous Mo-V-Bi oxide for selective (amm)oxidation of light alkanes
S. Ishikawa, Y. Goto, Y. Kawahara, S. Inukai, N. Hiyoshi, N. F. Dummer, T. Murayama, A. Yoshida, M. Sadakane, W. Ueda
Chem. Mater., 29, 2939-2950 (2017) - Hydrothermal Synthesis of a Layered-type W-Ti-O Mixed Metal Oxide and its Solid Acid Activity
T. Murayama, K. Nakajima, J. Hirata, K. Omata, E. J. M. Hensen, W. Ueda
Catal. Sci. Tech., 7, 243-250 (2017) - Identification of the catalytically active component of Cu-Zr-O catalyst for the hydrogenation of levulinic acid to γ-valerolactone
S. Ishikawa, D. Jones, S. Iqbal, R. Christian, D. J Morgan, D. J. Willock, P. Miedziak, J. K. Bartley, J. Edwards, T. Murayama, W. Ueda, G. Hutchings,
Green Chem., 19, 225-236 (2017) - Polyoxometalate-Assisted, One-Pot Synthesis of a Pentakis((triphenylphosphane)gold)ammonium(2+) Cation Containing Regular Trigonal-Bipyramidal Geometries of Five Bonds to Nitrogen
K. Nomiya, K. Endo, Y. Murata, S. Sato, S. Shimazaki, S. Horie, E. Nagashima, Y. Yasuda, T. Yoshida, S. Matsunaga, T. Matsubara
Inorg. Chem., 57, 1504-1516 (2018) - The Symmetric Raman Tensor Contributes to Chiral Vibrational Sum Frequency Generation from Binaphthyl Amphiphile Monolayers on Water – Study of Electronic Resonance Amplitude and Phase Profiles
M. Okuno, D. Ishikawa, W. Nakanishi, K. Ariga, T. Ishibashi
J. Phys. Chem. C, 121, 11241-11250 (2017) - pH-Responsive Cotton Effects in the d-d Transition Band of Self-Assembling Copper (II) Complexes with a Cholesteryl-Armed Ligand
T. Sagami, S. Umemoto, Y. O. Tahara, M. Miyata, Y. Yonamine, D. Ishikawa, T. Mori, K. Ariga, H. Miyake, S. Shinoda,
Bull. Chem. Soc. Jpn., 90, 739-745 (2017) - Mechanically Induced Opening-Closing Movements of Binaphthyl Molecular Pliers: Digital Phase Transition v.s. Continuous Conformational Change
T. Mori, D. Ishikawa, Y. Yonamine, Y. Fujii, J. P Hill, I. Ichinose, K. Ariga, W. Nakanishi
ChemPhysChem, 18, 1470-1477 (2017) - Novel Preparation of Poly(3,4-ethylene dioxythiophene)-Poly(styrenesulfonate)-Protected Noble Metal Nanoparticles as Organic-Inorganic Materials
S. Hata, T. Omura, K. Oshima, Y. Du, Y. Shiraishi, N. Toshima
Bull. Soc. Photogr. Imag. Jpn., 27, 13-18 (2017) - Electrochemical Production of Glycolic Acid from Oxalic Acid Using a Polymer Electrolyte Alcohol Electrosynthesis Cell Containing a Porous TiO2 Catalyst
M. Sadakiyo, S. Hata, X. Cui, M. Yamauchi
Sci. Rep., 3, 17032 (2017) - Improved Thermoelectric Behavior of Poly(3,4-ethylene dioxythiophene)-Poly(styrenesulfonate) using Poly(N-vinyl-2-pyrrolidone)-coated GeO2 Nanoparticles
Y. Shiraishi, S. Hata, Y. Okawauchi, K. Oshima, H. Anno, N. Toshima
Chem. Lett., 46, 933-936 (2017) - Carbon neutral energy cycles using alcohols
T. Fukushima, S. Kitano, S. Hata, M. Yamauchi
Sci. Tech. Adv. Mater., 19, 142-152 (2018) - A Systematic Study of the Mass Transport, Kinetic and Thermodynamic Properties of the FeIII/II Process at Glassy Carbon and Boron-Doped Diamond Electrodes
M.Y. Lin, J.Z. Li, D.W. Pan, A.M. Bond, J. Zhang
Electrochim. Acta, 249, 421-430 (2017) - Speciation determination of iron and its spatial and seasonal distribution in coastal river
Y. Zhu, X.P. Hu, D.W. Pan,H.T. Han, M.Y. Lin, Y. Lu, C.C. Wang, R.L. Zhu
Sci. Rep., 8(1), 2576 (2018) - An electrochemical sensor based on reduced graphene oxide/gold nanoparticles modified electrode for determination of iron in coastal waters
Y. Zhu, D.W. Pan, X.P. Hu, H.T. Han, M.Y. Lin, C.C. Wang
Sensor Actuat B-Chem., 243, 1-7 (2017) - Role of the Acid Site for Selective Catalytic Oxidation of NH3 over Au/Nb2O5
Mingyue Lin*, Baoxiang An, Nao Niimi, Yohei Jikihara, Tsuruo Nakayama, Tetsuo Honma, Takashi Takei, Tetsuya Shishido, Tamao Ishida, Masatake Haruta, and Toru Murayama*
ACS Catalysis, 9, 1753-1756 (2019) - Supported gold cluster catalysts prepared by solid grinding using a non-volatile organogold complex for low-temperature CO oxidation and the effect of potassium on gold particle size
Luong Xuan Dien, Tamao Ishida*, Ayako Taketoshi, Duc Q Truong, Huynh Dang Chinh, Tetsuo Honma, Toru Murayama, Masatake Haruta*
Applied Catalysis B: Environmental, 241, 539-547 (2019) - A zeolitic vanadotungstate family with structural diversity and ultrahigh porosity for catalysis
Zhenxin Zhang, Qianqian Zhu, Masahiro Sadakane, Toru Murayama, Norihito Hiyoshi, Akira Yamamoto, Shinichi Hata, Hisao Yoshida, Satoshi Ishikawa, Michikazu Hara, Wataru Ueda
Nature communications, 9, 3789 (2018) - The Effects of Dopants on the Cu–ZrO2 Catalyzed Hydrogenation of Levulinic Acid
Jun Hirayama, Igor Orlowski, Sarwat Iqbal, Mark Douthwaite, Satoshi Ishikawa, Peter J Miedziak, Jonathan K Bartley, Jennifer Edwards, Qian He, Robert L Jenkins, Toru Murayama, Christian Reece, Wataru Ueda, David J Willock, Graham J Hutchings
The Journal of Physical Chemistry C, in press, (2019) - Versatile etherification of alcohols with allyl alcohol by a titanium oxide-supported molybdenum oxide catalyst: gradual generation from titanium oxide and molybdenum oxide
Yoshihiro Kon, Tadahiro Fujitani, Takuya Nakashima, Toru Murayama, Wataru Ueda
Catalysis Science & Technology, 8, 4618-4625 (2018) - W-Ti-O Mixed Metal Oxide Catalyzed Dehydrative Cross-etherification of Alcohols
Akira Yada, Toru Murayama, Jun Hirata, Takuya Nakashima, Masanori Tamura, Yoshihiro Kon,* Wataru Ueda*
Chemistry letters, 47, 447-449 (2018) - Selective adsorption of 1,3-dimethyltrisulfane (DMTS) responsible for aged odour in Japanese sake using supportd gold nanoparticles
H. Murayama, Y. Yamamoto, M. Tone, T. Hasagewa, M. Kimura, T. Ishida, A. Isogai, T. Fujii, M. Okumura, M. Tokunaga
Sci. Rep., 8, 16064 (2018) - Cobalt hematoporphyrin inhibits CLEC-2–podoplanin interaction, tumor metastasis, and arterial/venous thrombosis in mice
Nagaharu Tsukiji, Makoto Osada, Tomoyuki Sasaki, Toshiaki Shirai, Kaneo Satoh, Osamu Inoue, Norihiko Umetani, Chihiro Mochizuki, Tamio Saito, Soichi Kojima, Hideyuki Shinmori, Yukio Ozaki and Katsue Suzuki-Inou
Blood adv., 2, 2214-2225 (2018) - Determination of iron in seawater: from the laboratory to in situ measurements
Mingyue Lin, Xueping Hu, Dawei Pan*, Haitao Han
Talanta, 188, 135-144 (2018) - Room temperature carbon monoxide oxidation based on two-dimensional gold-loaded mesoporous iron oxide nanoflakes
Yusuf Valentino Kaneti, Shunsuke Tanaka, Yohei Jikihara, Tsuruo Nakayama, Yoshio Bando, Masatake Haruta, Md. Shahriar A. Hossain, Dmitri Golberg and Yusuke Yamauchi,
Chemical Communications, 54, 8514-8517 (2018) - Bulk Vanadium Oxide versus Conventional V2O5/TiO2: NH3-SCR Catalysts Working at a Low Temperature Below 150oC
Yusuke Inomata, Shin-ichi Hata, Makoto Mino, Eiji Kiyonaga, Keiichiro Morita, Kenji Hikino, Kazuhiro Yoshida, Hiroe Kubota, Takashi Toyao, Ken-ichi Shimizu, Masatake Haruta, Toru Murayama*
ACS Catalysis, 9, 9327-9331 (2019) - High Dimensionally Structured W-V Oxides as Highly Effective Catalysts for Selective Oxidation of Toluene
Toru Murayama*, Satoshi Ishikawa, Norihito Hiyoshi, Yoshinori Goto, Zhenxin Zhang, Takashi Toyao, Ken-ichi Shimizu*, Shutoku Lee, Wataru Ueda*,
Catalysis Today, in press (2019) - CO oxidation over Au/ZnO: Unprecedented Change of the Reaction Mechanism at a Low Temperature Caused by a Different O2 Activation Process
Takashi Fujita, Tamao Ishida*, Kohei Shibamoto, Tetsuo Honma, Hironori Ohashi, Toru Murayama*, Masatake Haruta
ACS Catalysis, 9, 8364-8372 (2019) - Oxidative Esterification of Aliphatic Aldehydes and Alcohols with Ethanol over Gold Nanoparticle Catalysts in Batch and Continuous Flow Reactors
Ayako Taketoshi, Tamao Ishida, Toru Murayama, Tetsuo Honma, Masatake Haruta
Applied Catalysis A: General, 585, 117169 (2019) - Ultra-Low Temperature CO Oxidation Activity of Octahedral Site Cobalt Species in Co3O4 Based Catalysts: Unravelling the Origin of Unique Catalytic Property
Tinku Baidya, Toru Murayama, Subramanian Nellaiappan, Nirmal Kumar Katiyar, Parthasarathi Bera, Olga Safonova, Mingyue Lin, Kaustubh R Priolkar, Samapti Kundu, Bolla Srinivasa Rao, Patrick Steiger, Sudhanshu Sharma, Krishanu Biswas, Swapan Kumar Pradhan, Lingaiah Nakka, Kirtiman Deo Malviya, Masatake Haruta
The Journal of Physical Chemistry C, 123, 19557–19571 (2019) - Influence of the structure of trigonal Mo-V-M3rd oxides (M3rd = -, Fe, Cu, W) on catalytic performances in selective oxidations of ethane, acrolein, and allyl alcohol
Satoshi Ishikawa, Toru Murayama, Benjamin Katryniok, Franck Dumeignil, Marcia Araque, Svetlana Heyte, Sébastien Paul, Yudai Yamada, Mizuki Iwazaki, Nagisa Noda, Wataru Ueda
Applied Catalysis A: General, 584, 117151 (2019) - Effect of Supported MAO Cocatalysts in Ethylene Polymerization and Ethylene/1-Hexene Copolymerization Using Cp*TiCl2(O-2,6-iPr2C6H3) Catalyst
Palawat Unruean, Wannida Apisuk, Youhei Kawabata, Toru Murayama, Boonyarach Kitiyanan, and Kotohiro Nomura*
Molecular Catalysis, 475, 110490 (2019) - Low-temperature NH3-SCR Activity of Nanoparticulate Gold Supported on a Metal Oxide’
Yusuke Inomata, Makoto Mino, Sinichi Hata, Eiji Kiyonaga, Keiichiro Morita, Kenji Hikino, Kazuhiro Yoshida, Masatake Haruta, and Toru Murayama*
Journal of the Japan Petroleum Institute, 62, 234-243 (2019) - Dehydrative Allylation of Amine with Allyl Alcohol by Titanium Oxide Supported Molybdenum Oxide Catalyst
Yoshihiro Kon*, Takuya Nakashima, Tadahiro Fujitani, Toru Murayama, Wataru Ueda*
Synlett, 30(3), 287-292 (2019) - Redox-Active Zeolitic Transition Metal Oxides Based on ε-Keggin Units for Selective Oxidation
Zhenxin Zhang*, Satoshi Ishikawa, Qianqian Zhu, Toru Murayama, Masahiro Sadakane, Michikazu Hara, Wataru Ueda*
Inorganic chemistry, 58, 9, 6283-6293 (2019) - Ablation controlled laser desorption/ionization mass spectrometry by using improved transmission geometry
Kohei Shibamoto, Daisuke Furuya, Takashi Fujita
Chemical Physics Letters, 738, 136892 (2019) - Snake venom rhodocytin induces plasma extravasation via toxin-mediated interactions between platelets and mast cells
Yuki Nakamura, Tomoyuki Sasaki, Chichiro Mochizuki, Kayoko Ishimaru, Schuichi Koizumi, Hideyuki Shinmori, Katsue Suzuki-Inoue, Atsuhito Nakao
Scientific Reports, 9, 15958 (2019) - Dendrimer-templated Synthesis and Characterization of Tin Oxide Quantum Dots Deposited on Silica Glass Substrate
Yusuke Inomata, Ken Albrecht, Naoki Haruta, Kimihisa Yamamoto*
Chemistry of Materials, 31, 8373–8382 (2019) - DNA origami nanoplate-based emulsion with nanopore function
Daisuke Ishikawa, Yuki Suzuki, Chikako Kurokawa, Masayuki Ohara, Misato Tsuchiya, Masamune Morita, Miho Yanagisawa, Masayuki Endo, Ryuji Kawano, Masahiro Takinoue
Angewandte Chemie International Edition, 58, 15299–15303 (2019) - Multi-dimensional Crystal Structuring of Complex Metal Oxide Catalysts of Group V and VI Elements by Unit-Assembling
Satoshi Ishikawa, Zhenxin Zhang, Toru Murayama, Norihito Hiyoshi, Masahiro Sadakane, Wataru Ueda*
Topics in Catalysis, 62, 1157–1168 (2019) - CO2 Reduction to Methanol on Au/CeO2 Catalysts: Mechanistic Insights from De-Activation and SSITKA Measurements
Azita Rezvani, Ali Abdel-Mageed, Tamao Ishida, Toru Murayama, Magdalena Parlinska-Wojtan, Jürgen R. Behm
ACS Catalysis, 10, 3580-3594 (2020) - Oxidation of β-Nicotinamide adenine dinucleotide (NADH) by Au Cluster and Nanoparticle Catalysts Aiming for Coenzyme Regeneration in Enzymatic Glucose Oxidation
Jun-ichi Nishigaki, Tamao Ishida, Tetsuo Honma, Masatake Haruta
ACS Sus. Chem. Eng., 8(28), 10413-10422 (2020) - Synthesis of Bulk Vanadium Oxide with a Large Surface Area Using Organic Acids and Its Low-Temperature NH3-SCR Activity
Yusuke Inomata, Shinichi Hata, Eiji Kiyonaga, Keiichiro Morita, Kazuhiro Yoshida, Masatake Haruta, Toru Murayama*
Catalysis Today, 376, 188-196 (2021) - C, N Co-Decorated Alumina-Supported Au Nanoparticles: Enhanced Catalytic Performance for Selective Hydrogenation of Acetylene
Yuan Zhang, Xun Sun, Yali Zhao, Huijuan Su, Toru Murayama, Caixia Qi*
Topics in Catalysis, 64, 197-205 (2021) - Gold Nanoparticles Supported on Ce–Zr Oxides for Selective Hydrogenation of Acetylene
Xiaoyue Hua, Yuhua Zheng, Zixuan Yang, Libo Sun, Huijuan Su, Toru Murayama, Caixia Qi*
Topics in Catalysis, 64, 206-214 (2021) - Preparation of Polyaniline Microtubes as the Gold Catalyst Support with Improved Catalytic Performances for the Reduction of Nitrophenols
Libo Sun, Lin Jiang, Jie Zhang, Toru Murayama, Miao Zhang, Yuhua Zheng, Huijuan Su, Caixia Qi*
Topics in Catalysis, 64, 215-223 (2021) - Influence of the Support in Aqueous Phase Oxidation of Ethanol on Gold/Metal Oxide Catalysts Studied by ATR-IR Spectroscopy under Working Conditions
Ammara Waheed, Xianwei Wang, Nobutaka Maeda, Daniel.M. Meier, Tamao Ishida, Toru Murayama, Masatake Haruta, Alfons Baiker*
Catalysis Communications, 148, 106183 (2021) - Bulk tungsten-substituted vanadium oxide for low-temperature NOx removal in the presence of water
Yusuke Inomata, Hiroe Kubota, Shinichi Hata, Eiji Kiyonaga, Keiichiro Morita, Kazuhiro Yoshida, Norihito Sakaguchi, Takashi Toyao, Ken-ichi Shimizu, Satoshi Ishikawa, Wataru Ueda, Masatake Haruta, and Toru Murayama*
Nature Communications, 12, 557 (2021) Editors' Highlights
[Web Page]External Link - CO2 Reduction to Methanol on Au/CeO2 Catalysts: Mechanistic Insights from Activation/Deactivation and SSITKA Measurements
Azita Rezvani, Ali M. Abdel-Mageed, Tamao Ishida, Toru Murayama, Magdalena Parlinska-Wojtan, Jürgen R. Behm*
ACS Catalysis, 10, 3580-3594 (2020) - Ligand Effect of Gold Colloid in the Preparation of Au/Nb2O5 for CO Oxidation
Mingyue Lin, Chihiro Mochizuki, Baoxiang An, Tetsuo Honma, Masatake Haruta, Tamao Ishida, Toru Murayama*
Journal of Catalysis, 389, 9-18 (2020) - Features of Nb2O5 as a Metal Oxide Support of Pt and Pd Catalysts for Selective Catalytic Oxidation of NH3 with High N2 Selectivity
Mingyue Lin, Baoxiang An, Takashi Takei, Tetsuya Shishido, Tamao Ishida, Masatake Haruta, Toru Murayama*
Journal of Catalysis, 389, 366–374 (2020) - Low-Temperature Propylene Epoxidation Activity of CuO-CeO2 Catalyst with CO + O2: Role of Metal-Support Interaction on the Reducibility and Catalytic Property of CuOx Species
Tinku Baidya, Tanmoy Mazumder, Konstantin Koltunov, Pravin Likhar, Adam Clark, Khushbo Tiwari, Vladimir I. Sobolev, Soumitra Payra, Toru Murayama, Mingyue Lin, Parthasarathi Bera, Sounak Roy, Krishanu Biswas, Olga Safonova, Bolla Srinivasa Rao, Masatake Haruta
The Journal of Physical Chemistry C, 124(26), 14131–14146 (2020) - Gold Nanoparticles Supported on Nb2O5 for Low-Temperature CO Oxidation and as Cathode Materials for Li-ion Batteries
Luong X Dien*, Quang D Truong, Toru Murayama*, Huynh D Chinh, Ayako Taketoshi, Itaru Honma, Masatake Haruta, Tamao Ishida*
Applied Catalysis A: General, 603, 117747 (2020) - Elucidation of Active Sites of Gold Nanoparticles on Acidic Ta2O5 Supports for CO Oxidation
Mingyue Lin, Chihiro Mochizuki, Baoxiang An, Yusuke Inomata, Tamao Ishida, Masatake Haruta, Toru Murayama*
ACS Catalysis, 10(16), 9328–9335 (2020) - Importance of Size and Contact Structure of Gold Nanoparticles for Genesis of Unique Catalysis
Tamao Ishida, Toru Murayama, Ayako Taketoshi, Masatake Haruta
Chemical Reviews, 120, 464–525 (2020) - Synthesis of zeolitic Mo-doped vanadotungstates and their catalytic activity for low-temperature NH3-SCR
Meilin Tao, Satoshi Ishikawa, Toru Murayama, Yusuke Inomata, Akiho Kamiyama, Wataru Ueda*
Inorganic Chemistry, 60(7), 5081-5086 (2021)
Reviews
- Modern Alchemy to Turn Gold into Excellent Catalysts
Masatake Haruta
5th International Symposium on Atomic Level Characterization for New Materials and Devices ’05, Big Island, Hawaii, USA, December 4-9, 2005: JSPS 141 Committee Activity Report, 17-22 (2006) - Au NP-catalysed Propene Epoxidation by Dioxygen and Dihydrogen
J. Kawahara, M. Haruta
Nanoparticles and Catalysis, D. Astruc, Ed., Wiley-VCH Weinheim, Chapter 14, pp.457-473 (2008)
[Web Page]External Link - Relevance of Metal Nanoclusters Size Control in Gold(0) Catalytic Chemistry
M. Haruta
Metal Nanoclusters in Catalysis and Materials Science: The Issue of Size Control, B.Corain,G. Schmid, N. Toshima Ed., Elsevier B. V, Amsterdam, Chapter 9, pp.183-199 (2008)
[Web Page]External Link - Epoxidation of Propylene with Hydrogen-Oxygen Mixtures, Mechanism in Homogeneous and Heterogeneous Epoxidation Catalysis
M. Haruta, J. Kawahara
S. T. Oyama ed., Elsevier B. V., Amsterdam, Chapter 10, pp.285-300 (2008)
[Web Page]External Link - Nanoparticulate Gold Catalysts
M. Haruta
Science of Metals and Semiconductor Nanoparticles, edited by Chemical Society of Japan, KAGAKUDOUJIN, 101-107 (2012)
[Web Page]External Link - Novel Catalysis by Gold: from Nanoparticles to Clusters
M. Haruta
Mol. Sci., 6, A0056 (2012)
[Web Page]External Link - Gas phase propene epoxidation over coinage metal catalysts
J. Huang, M. Haruta
Research on Chemical Intermediates, 38, 1-24 (2012)
[Web Page]External Link - Heterogeneous catalysis by gold
T. Takei, T. Akita, I. Nakamura, T. Fujitani, M. Okumura, K. Okazaki, J. Huang, T. Ishida, M. Haruta
Advances in Catalysis, 55, B.C. Gates, F.C. Jentoft ed., Elsevier, Chapter 1, 1-124 (2012)
[Web Page]External Link - Technologies and Applications of Environmentally-friendly Ceramics
T. Takei, M. Haruta
M. Nogami ed., CMC Publishing, Tokyo, pp.207-220 (2007)
[Web Page]External Link - Particle Size and Support Effect on Noble Metal Catalysts
M. Haruta
Introduction to Nanotechnology Chemistry and Materials, Kyoritsu Shuppan, Tokyo, Chapter 7, pp.85-102 (2007)
[Web Page]External Link - Exploitation and Market Development of Nanoparticulate Gold Catalyst Materials
Y. Shimojo, M. Haruta
Engineering Materials, 61 (12), 50-54 (2013)
[Web Page]External Link - Unique Catalytic Performance of Supported Gold Nanoparticles in Oxidation0
Y. Yu, J. Huang, T. Ishida, M. Haruta
Modern Heterogeneous Oxidation Catalysis: Design, Reactions and Characterization, N. Mizuno ed., WILEY-VCH, Chapter 3, pp.77-124 (2009)
[Web Page]External Link - Nanoparticulate Gold Catalysts
Y. Shimojo, M. Haruta
Modern Technology and Applications of Metal Nano-and Microparticles, (T. Yonezawa Ed.), CMC Publishing Co. Ltd., Chapter 1.1 Application, 135-144 (2013)
[Web Page]External Link - Chance and necessity : my encounter with gold catalysts
M. Haruta
Angew. Chem. Int. Ed., 53, 52-56 (2014)
[Web Page]External Link - Angewandte Author Profile
M. Haruta
Angew. Chem. Int. Ed., 53, 2-3 (2014)
[Web Page]External Link - Heterogeneous catalysis by Gold Clusters
J. Huang, M. Haruta
Bridging Heterogeneous and Homogeneous Catalysis: Concepts, Strategies, and Applications, 1, C. Li, Y. Liu eds., Wiley-VCH: Weinheim, 397-424 (2014) - Size- and Structure-specificity in Catalysis by Gold Clusters
A. Taketoshi, M. Haruta
Chem. Lett., 43(4), 380-387 (2014)
[Web Page]External Link - New Findings in CO Oxidation (Chapter 1)
Y. Shimojo, M. Haruta
Gold Catalysis : Preparation, Characterization and Applications in the Gas and Liquid Phase, ed. by Laura Prati, Albert Villa, Pan Stanford Publishing: Singapore, (2014) in press - Role of Water in CO Oxidation on Gold Catalysts
T. Fujitani, I. Nakamura, M. Haruta
Catal. Lett., 144, 1475-1486 (2014)
[Web Page]External Link - A Career in Catalysis: Masatake Haruta
M. Okumura, T. Fujitani, J. Huang, T. Ishida
ACS Catal., 5, 4699–4707 (2015)
[Web Page]External Link - New Findings in CO Oxidation
Y. Shimojo, M. Haruta
Gold Catalysis: Preparation, Characterization and Applications, L. Prati, A. Villa, Ed., Pan Stanford Publishing, pp. 285–310 (2015) - Synergetic Combination of an Enzyme and Nanoparticulate Gold Catalysts
A. Taketoshi, M. Haruta
Kagaku To Kogyo, 89, 336-340 (2015) - Gold Catalysts ―from Nanoparticles to Clusters―
A. Taketoshi
Chemistry & Education, 64, 22-23 (2016) - Gas Phase Propene Epoxidation with Oxygen
M. Haruta, K. Imai
CSJ Current Review 21, “New Aspects of Reactive Oxygen and Free Radicals”, edited by Chemical Society of Japan, KAGAKUDOUJIN, (2016) - C–H Functionalization by Supported Palladium and Gold Catalysts
T. Ishida, M. Tokunaga
Annual Survey of Catalytic Science and Technologies 2016, in press - Advances in Gold Catalysis and Understanding the Catalytic Mechanism
1. T. Ishida, H. Koga, M. Okumura, M. Haruta
Chem. Rec., 16, 2278–2293 (2016) - Supported Gold Nanoparticles Leading to Green Chemistry
T. Ishida, M. Haruta
Nanotechnology in Catalysis: Applications in the Chemical Industry, Energy Research, and Environment Protection, ed. by Bert F. Sels, M. van de Voorde, Wiley-VCH, - Gold Rush in 21st Century
M. Haruta
Vol.51, No.11, Journal o the Vacuum Society of Japan, pp.719-720 (2008)
[Web Page]External Link - Gold Rush in 21st Century: Gold Nanoparticles
M. Haruta
GOLD, National Museum of Nature and Science, The Mainichi Newpapers, NHK Promotion, 129-132 (2008) - Novel Catalysis by Gold: A Modern Alchemy
M. Haruta
Vol.51, No.11, Journal o the Vacuum Society of Japan, pp.721-726 (2008)
[Web Page]External Link - Catalytic Action of Gold Nanoparticles. Air Purification and Green Chemistry
M. Haruta
Vol.64,No.1, Kagaku, pp31-34 (2009) - Gold Nanoparticles Catalysts for Air Purification and Green Chemistry
T.Takei,M.Haruta
22, Materials Integration, 38-44 (2009) - Development of Catalytic Performance by Minmizing Gold Particle Size
M. Haruta
44, Ceramics Japan 2009, pp.377-381 (2009) - Gold does not cheat: Catalysis by Gold Founded by Hypothesis
M. Haruta
62, Chemistry and Chemical Industry 2009, pp.634-636 (2009) - Gas-Phase Propylene Epoxidation over Gold Catalysts
M. Haruta, J. Huang
51, Catalysts & Catalysis 2009, pp.512-517 (2009) - Motive Power of Chemistry Innovation is Catalysis
M. Haruta
53, Catalysts and Catalysis, 63 (2011) - Supported Gold Nanparticulate Catalysts on Metal Oxides
T. Takei
61, Chemical Industry, 505-510 (2010)
[Web Page]External Link - Preparation of Supported Gold Nanparticulate and Their Applications
T. Takei,T. Ishida, M. Haruta
2, Funtai Gijutsu, 44-51 (2010) - Base Metal OxidesActive for Low Temperature CO Oxidation
M. Haruta
Vol.32 No.2, J. Surf. Sci. Soc. Jpn., 70-75 (2011)
[Web Page]External Link - I Basics, 1 Introduction of Catalysts
M. Haruta
Catalysis Handbook, The Catalysis Society of Japan, 3-10 (2008) - What does it change by size?
M. Haruta
Gold nanotechnology: Fundamentals and Applications, M. Haruta ed., CMC Publishing, Tokyo, Chapter 1, 3-15 (2009)
[Web Page]External Link - Introduction of Deposition Technique for Gold Nanoparticles and Clusters
M. Haruta
Gold nanotechnology: Fundamentals and Applications, M. Haruta ed., CMC Publishing, Tokyo, Chapter 8, 107-115 (2009)
[Web Page]External Link - Applications of Gold Nanoparticles Catalysts into Environmental Conservation
M. Haruta
Gold nanotechnology: Fundamentals and Applications, M. Haruta ed., CMC Publishing, Tokyo, Chapter 25, 324-345 (2009)
[Web Page]External Link - Deposition of Au Nanoparticles onto Metal Oxides
T. Takei
Gold nanotechnology: Fundamentals and Applications, M. Haruta ed., CMC Publishing, Tokyo, Chapter 9, 116-126 (2009)
[Web Page]External Link - Deposition of Au Nanoparticles onto Carbons and Polymers
T. Ishida
Gold nanotechnology: Fundamentals and Applications, M. Haruta ed., CMC Publishing, Tokyo, Chapter 10, 127-134 (2009)
[Web Page]External Link - Support and Size Effect of Catalysis by Gold
H. Ohashi
Gold nanotechnology: Fundamentals and Applications, M. Haruta ed., CMC Publishing, Tokyo, Chapter 17, 220-232 (2009)
[Web Page]External Link - Control of Structure and Properties of Silicas (Chapter 1)
T. Takei
Properties, Surface Modification and Dispersion Technology of Silica Particles and its Applications, Gijyutujoho Kyoukai, 3-19 (2009)
[Web Page]External Link - Gold Nanoparticles Catalysts
T. Ishida
Chemistry of Coordination Space-Latest Technology and Applications, (S. Kitagawa Ed.), CMC Publishing Co. Ltd., Chapter 5.1 Reaction, 198-205 (2009)
[Web Page]External Link - Preparattion of Porous Materials (Mesopore),Silica Gel
T. Takei
Encyclopedia of Ceramics, Asakura, 365-369 (2009)
[Web Page]External Link - Fine Particles – Materials and Function (Chapter 4)
T. Takei
3rd edition Basic Princeples of Modern Colloid Science, (The Chemical Society of Japan), Maruzen, 133-140 (2009)
[Web Page]External Link - Gold Nanoparticles bring a fresh sensitivity to the world of material science
M. Haruta
TMU-Beyond, 1, Tokyo Metropolitan Univesity Liaison Office, 2 (2014)
[Web Page]External Link - Generation of Novel Catalytic Functions by Nanoparticulation of Gold
A. Taketoshi, M. Haruta
Bunseki Kagaku, 63(12), 959-964 (2014)
[Web Page]External Link
Patents
- T. Ishida, R. Makiyama, M. Haruta
“Solid Polymer Material Carrying Noble Metal Particulate, Preparation Method thereof and Catalyst” JP2007-082287, Filing Date:Mar 27, 2007 Applied
Applied, Tokyo Metropolitan University - M. Haruta, Y. Yu, J. Huang, A. Taketoshi, T. Ishida, T. Akita, A. Ogata, H. Kim
“Gold Cluster Catalysts and its Production Methods” JP2012-133329, Filing Date:Jun 12, 2012 Applied
Applied, Tokyo Metropolitan University - M. Haruta, S. Takenouchi, A. Taketoshi, T. Takei
“Oxidation Catalysts and Production Methods for Organic Oxygenates” JP2012-194605, Filing Date:Sep 04, 2012 Applied
Applied, Tokyo Metropolitan University - A. Taketoshi, M. Haruta, S. Oe
“Oxidation Catalysts” JP2011-264534, Filing Date:Dec 02, 2011 Applied
Applied, Tokyo Metropolitan University - M. Haruta, T. Ishida, I. Okuda, K. Kuroda, N. Kinoshita, J. Suenaga, Y. Yamaguchi
“Method for Dispersing and Fixing Gold Fine Particle to Carrier, Gold Fine Particle-deposited Carrier Obtained Thereby, Catalyst and Colorant” JP2007-106198, Filing Date:Apr 13, 2007 Applied
Applied, Tokyo Metropolitan University - M. Haruta, T. Ishida, N. Kinoshita, K. Kuroda, H. Okatsu
“Methods for depositing Au fine particles on support materials and the materials made by them” JP2008-067090, Filing Date:Mar 01, 2008 Applied
Applied, Tokyo Metropolitan University - H. Ohashi, M. Haruta, T. Takei, T. Ishida
“Methods for depositing Au fine particles on support materials and the materials made by them” JP2008-091587, Filing Date:Mar 01, 2008 Applied
Applied, Tokyo Metropolitan University - T. Takei, J. Suenaga, K. Kuwano, H. Ohashi, T. Ishida, M. Haruta
“Highly Active Catalysts and its Preparation” JP2008-179978, Filing Date:Jul 01, 2008 Applied
Applied, Tokyo Metropolitan University - Y. Iizuka, T. Tamai, T. Hayashi, I. Okuda, M. Haruta
“Production of Cycloolefins and the Catalysts for these Selective Hydrogenations” JP2009-36389, Filing Date:Feb 01, 2009 Applied
Applied, Tokyo Metropolitan University - M. Haruta, J. Huang, T. Takei, T. Akita
“Production of Propylene Oxide” JP2009-61683, Filing Date:Mar 01, 2009 Applied
Applied, Tokyo Metropolitan University - Y. Sasaki, Y. Asako, T. Ishida, M. Haruta
“Production of Metal-coated Particles” JP2010-031057, Filing Date:Feb 16, 2010 Applied
Applied, Nippon Shokubai Co. Ltd., Tokyo Metropolitan University - T. Takei, N. Iguchi, M. Haruta
“Gold Catalysts for Ethanol Oxidation and its Use for the Production of Acetaldehyde and Acetic Acid” JP2010-065746, Filing Date:Mar 23, 2010 Applied
Applied, Tokyo Metropolitan University - M. Haruta, T. Takei, N. Fujita
“Catalysts for Catalytic Combustion and Decomposition Method of Ethylene” JP2010-206130, Filing Date:Sep 14, 2010 Applied
Applied, Tokyo Metropolitan University - T. Ishida, M. Haruta, H. Watanabe
“Highly Active Base Metal Oxide Catalysts for Selective Oxidaion Reactions” JP2010-206129, Filing Date:Sep 14, 2010 Applied
Applied, Tokyo Metropolitan University - M. Ikegami, T. Matsumoto, T. Nkayama, A. Ogata, K. Kim, M. Haruta, T. Takei
“Gas Purification Methods and its Apparatus using Low Temperature Plasma and Catalytic Filter” JP2010-206073, Filing Date:Sep 14, 2010 Applied
Applied, NBC Meshteck, AIST, Tokyo Metropolitan University - E. Kiyonaga, K. Hikino, K. Morita, M. Haruta, T. Murayama, M. Mino
“Thermal power system” JP6077190, Jan 20, 2017 Registered
Applied, The Chugoku Electric Power Co., Tokyo Metropolitan University - M. Haruta, T. Ishida, D. X. Luong,
“Producation of gold composite materials” JP2017-042768, Filing Date:Mar 07, 2017 Applied
Applied, Tokyo Metropolitan University
Invited lectures
- Catalysis by Gold: Nanoparticles and Clusters for Green Sustainable Chemistry
Masatake HARUTA
International Symposium on Small Particles and Clusters, Gotenburg, Sweden, 2006.07.01 (Plenary) - Modern Alchemy: Catalysis by Gold Nano-particles
Masatake HARUTA
PIRE-ECCI/ICMR Summer Conference, University of California, Santa Barbara, USA, 2006.08.01 (Invited) - Active Sites in Heterogeneous Catalysis by Gold
M. Haruta
5th Xiamen Workshop on Surface Science: China-Japan Symposium on Selective Oxidation Catalysis, Xiamen, China, 2007.04.22 - Size and Support Effect in the Catalysis by Gold Nanoparticles
M. Haruta
16th International Symposium on Rectivity of Solids, Minneapolis, USA, 2007.06.03 (Plenary) - Active Sites in the Catalysis by Gold
M. Haruta
25th Taiwanese Catalysis and Reaction Engineering Conference, Tatung University, Taipei, Taiwan, 2007.07.06 (Plenary) - Size and Support Effect in the Catalysis by Gold
M. Haruta
Seminar at National Taiwan University, Taipei, Taiwan, 2007.07.07 - Green Sustainable Chemistry through Gold Catalysts
M. Haruta
Seminar at National Cheng Kung University, Tainan, Taiwan, 2007.07.09 - Gas Phase Propylene Epoxidation over Gold Nanoparticles Deposited on Mesoporous Titanium Silicates (Keynote Lecture)
M. Haruta
The 234th ACS National Meeting, Boston, USA, 2007.08.19 - Deposition of Gold Clusters onto Macromolecular Complexes and Their Catalytic Performances
M. Haruta
12th IUPAC International Symposium on MacroMolecular Complexes (MMC-12), Fukuoka, Japan, 2007.08.30 - Structure of Nanoparticulate Gold Catalysts Observed with a TEM
M. Haruta, T. Akita
20th Catalysis Research Center International Symposium, In-situ Characterization of Catalysts-Presence and Future Aspects, Sapporo, Japan, 2007.09.21 - Catalytically Active States of Gold
M. Haruta
3rd China-Japan Workshop on Environmental Catalysis and Eco-Materials, Tsinghua University, Beijing, China, 2007.10.12 - Purification of Air in the Urban Environment by Nanoparticulate Gold Catalysts, ISSUE 2007
M. Haruta
International Symposium on Sustainable Urban Enviroment 2007, Tokyo Metropolitan University, Japan, 2007.11.09 - Catalysis of Gold Clusters Fixed in the Nanosapce of Metal Complex
M. Haruta
3rd International Symposium on Chemistry of Coordination Space (ISCCS), Hyogo, Japan, 2007.12.11 - Deposition of Gold Clusters onto Macromolecular Complexes and Their Catalytic Performances
M. Haruta
169th ICYS (International Center for Young Scientists) Special Seminar, National Institute for Materials Science, Tsukuba, Japan, 2007.12.14 (Invited) - Supported Gold Nanoparticles as a Key Catalyst for Green Sustainable Chemistry
M. Haruta
1st Singapore Catalysis Forum, Inst. Chem. Eng. Sci., Singapore, 2008.04.01 - Direct Deposition of Gold Nanoparticles onto Carbons and Polymers for Selective Catalysis in Liquid Phase
M. Haruta
14th International Congress on Catalysis (ICC) Pre-Symposium, Kyoto, Japan, 2008.07.01 - Gold Catalysts Leading to Green Sustainable Chemistry
M. Haruta
2nd STINT/SNU Summer School, Seoul, Korea, 2008.07.01 - From Gold to Green: Catalysis by Clusters
M. Haruta
Spain-Japan Joint Workshop on“Nanoscience and New Materials”, Tokyo, 2009.04.01 (Invited) - Novel Catalysis by Gold Clusters
M. Haruta
4th Taylor Conference on Catalysis”, Cardiff, UK, 2009.07.01 (Plenary) - Chemical Innovation by Gold Catalysts
M. Haruta
5th International Conference on Gold Science, Technology and Its Applications (GOLD2009), Heidelberg, Germany, 2009.07.01 (Plenary) - Simple Chemistry Catalyzed by Gold Clusters
M. Haruta
4th International Conference on Green and Sustainable Chemistry (GSC-4) & 2nd Asian-Oceanian Conference on Green and Sustainable Chemistry (AOC-2), Beijing, China, 2009.08.01 (Invited) - Preparation of Gold Catalysts
M. Haruta
Workshop on Au Catalysis & Its Industrial Application, Yantai, China, 2009.08.01 - Selective Oxidation and Hydrogenation by Supported Gold Catalysts
M. Haruta
The Inauguration of KAUST Catalysis Center (KCC), The KCC symposium on Catalysis, Jedda, Saudi Arabia, 2010.12.08 - Novel Chemistry by Nanoparticles and Clusters
M. Haruta
Chemistry Seminar, Université Bordeaux I, 2010.11.22 - Green Chemistry by Supported Gold Catalysts
M. Haruta
9th Japan-FranceWorkshop on Nanomaterials, Toulose, France, 2010.10.25 - Green Chemistry Catalyzed by Gold Clusters
M. Haruta
54thWelch Conference, Houston, USA, 2010.10.25 - Unique Catalysis by Gold Nanoparticles Deposited on Base Metal Oxides
M. Haruta
International Conference on Nanoscopic Colloid and Surface Science, Chiba, Japan, 2010.09.21 - Selective Oxidation and Hydrogenation of Biomass Derived Alcohols over Gold Catalysts
M. Haruta
6th Tokyo Conference on Catalytic Science and Technology & 5th Asia Pacific Congress on Catalysis (TOCAT6/APCAT5), Sapporo, Japan, 2010.07.12 - Novel Catalysis by Gold Clusters Leading to Green Chemistry
M. Haruta
Inaugural International Conf. on Molecular & Functional Catalysis(ICMF-1), Singapore, 2010.07.12 - Novel Catalysis by Supported Gold Clusters
M. Haruta
FUNDACION ARECES, Valencia, Spain, 2010.05.25 - Current and Future Applications of Gold Catalysts
M. Haruta
Workshop for the Opening of Yantai Gold Nanotechonogy Research Center, Yantai University, China, 2011.04.19 - Catalysis by Gold Clusters Leading to Green Chemistry
M. Haruta
Seminar for Celebration of 100th Anniversary of Tsinghua University, Tsinghua University, China, 2011.04.21 - Preparation of Supported Gold Clusters for Green Chemistry
M. Haruta
Colloids Materials 2011, Amsterdam, 2011.05.10 - Novel Catalysis by Supported Gold Clusters
M. Haruta
Seminar at Universite Catholique de Louvain, Louvain-la Neuve, 2011.05.13 - Catalytic Performance and Atomic Structure of Supported Gold Nanoparticles
M. Haruta
ALC'11, Seoul Olympic Parktel, 2011.05.22 - Nano-structures of Active Gold Catalysts
M. Haruta
13th Korea-Japan Symposium on Catalysis, Jeju Islands, Korea, 2011.05.25 - The Role of Perimeter Interfaces in the Catalysis by Supported Gold Nanoparticles
M. Haruta
Faraday Discussion 152: Gold, Cardiff University, UK, 2011.07.04 - Catalysis by Gold Nanoparticles Leading to Green Chemistry
M. Haruta
Seminar at Liverpool University, 2011.07.07 - Novel Catalysis by Gold Clusters Leading to Green Chemistry
M. Haruta
Gordon Conference, Mount Holyoke College, South Hadley, USA, 2011.07.24 - Stability and Catalytic Activity of Gold Nanoparticles Supported on Base Metal Oxides
M. Haruta
6th International & 8th Japan-China Joint Symposium on Calorimetry and Thermal Analysis, CATS2011, Tokyo Metroplitan University, 2011.08.02 - Gold Catalysts for Green Chemistry and Efficient Energy Conversion
M. Haruta
Workshop, Universtity of Castilla-La Mancha, 2011.09.15 - Supported Gold Nanoparticles Leading to Green Chemistry
M. Haruta
Composite Lake Louise, Canada, 2011.11.02 - Propene epoxidation over gold nanoparticules and clusters deposited on TS-1
M. Haruta
Evonik Meets Science, 2011.11.16 - Role of Perimeter Interfaces and Water in Catalysis by Gold Nanoparticles
M. Haruta
141 Workshop, Tokyo, 2011.11.19 - Simple Chemistry Catalyzed by Supported Gold Nanoparticles
M. Haruta
Catalysis for Fine Chemicals, Nara, 2011.12.08 - The role of perimeter interfaces in the genesis of catalysis by gold nanoparticles
M. Haruta
AMTC3 (Third International Symposium on Advanced Microscopy and Theoretical Calculations), Nagara-gawa Convention Center, Gifu, 2012.05.10 - Catalysis by gold nanoparticles and clusters leading to green chemistry
M. Haruta
2nd International Conference on Molecular and Functional Catalysis, Singapore, 2012.07.30 - Introductory talk for JST session
M. Haruta
The 6th International Conference on Gold Science, Technology, and its Applications (GOLD2012), Keio Plaza Hotel Tokyo, Tokyo, 2012.09.08 - Catalysis by gold clusters leading to simple chemistry
M. Harura
1st International Conference of NanoSquare, Osaka Prefecture University, 2013.02.04 - Bright future of gold catalysis research
M. Haruta
Academic Committie, Dalian Institute of Chemical Physics, China, 2013.03.28 - Novel Catalysis by Gold Nanoparticles: Support and Size Effect
M. Haruta
Young Coordination Chemist’s Summer School, Hakone, 2007.08.01 - Novel Catalysis by Gold Nanoparticles
M. Haruta
The 68th SCI-TECH Salon, Komaba Fucalty House, Tokyo, 2013.08.24 - Novel Catalysis by Gold: From Nanoparticles to Clusters
M. Haruta
The 7th Annual Meeting of Japan Society for Molecular Science, Kyoto TERRSA, Kyoto, 2013.09.24 - Modern Alchemy: Nanotechnology of Gold
M. Haruta
2013 Fall Meeting of Midorikai Tokyo Branch and General Meeting/Special Lectures of Nagoya Kougyoukai Tokyo Branch, Nakano SUNPLAZA, Tokyo, 2013.11.09 - When Gold is not Noble: Catalysis by Nanoparticles
M. Haruta
Tokyo Metropolitan University Special Lecture, TMU Auditorium, 2013.11.20 - Fine Structure and Unique Catalysis of Gold Nanoparticles
M. Haruta
JEOL The 34th R&D Executive Mixer, Imperial Hotel Tokyo, 2013.11.22 - Making Real Gold Nanoparticle Catalysts in Practical Use
M. Haruta
2013 AIST OB Association Lectures–The Road to Novel Prize–, AIST Kansai Center, Osaka, 2013.12.09 - Novel Catalysis of Gold Nanoparticles: Mechanisms and Future Applications
M. Haruta
The 3rd Symposium of JST-CREST (Basic technology of nano-interface), Akiba Hall, Tokyo, Japan, 2013.12.17 - Gold Nanoparticles Pioneers Simple Chemistry
M. Haruta
The 8th Public Lectures in Division of Nanoparticle/StructureApplication, The Society of Non-Tranditional Technology, –Novel Preparation Technique, Structure, and its Application of Nanoparticles–, The Chemical Society of Japan, Chemistry Hall, Tokyo, 2014.03.04 - Simple Chemistry by Gold Nanoparticle Catalysts
M. Haruta
The 4th Symposium of Green Chemistry, Cooperative Education and Research Center for Green Chemistry and Faculty of Science, Niigata University, Niigata, 2014.03.18 - Synergetic Combination of Enzyme and Gold Catalysts for Glucase Oxidation in Neutral Solution
M. Haruta
BIT's 4th Annual Global Congress of Catalysis 2013, Dalian World EXPOCenter, China, 2013.07.01 - Randomness & Nessecity : My Encounter with Gold Catalysis
M. Haruta
Zhang Dayu Lecture, Dalian Institute of Chemical Physics, 2013.09.26 - Simple Chemistry by Gold Nanoparticle Catalysts
M. Haruta
24th Banyu Fukuoka Symposium, Centennial hall Kyushu University School of Medicine, 2014.06.09 - Coincidence and Necessity: Encounter with Gold
M. Haruta
2015 Alumni eventof Tokyo Metropolitan University, Tokyo Metropolitan University International House, 2014.11.08 - Catalysis and Application of Gold Nanoparticles: What do we need to know and measure from now on?
M. Haruta
Science Council of Japan Public Lecture, ”Innovation Opened by Nanomaterials and Nanosensing”, Science Council of Japan Lecture Hall, 2014.12.18 - Heterogeneous catalysis by gold nanoparticles leading to green chemistry
M. Haruta
Université Catholique de Louvain, Belgium, Doctor Honoris Causa, 2014.05.27 - Novel catalysis by gold clusters
M. Haruta
The 3rd Frontier Chemistry Center International Symposium” Challenges at the Frontier of Chemical Sciences”, Hokkaido University, 2014.06.13 - Selective oxidation of ethanol with molecular oxygen on supported gold nanoparticles
M. Haruta
248th American Chemical Sciety National Meeting & Exposition, San Francisco Moscone Center, 2014.08.11 - Gold catalysts for simple chemistry
M. Haruta
Taishan Academic Forum, Yantai University, 2014.09.23 - CO oxidation on supported gold nanoparticles
M. Haruta
CRC-SU Joint International Symposium on Chemical Theory for Complex Systems, Stockholm University, 2014.10.30 - Gold-Catalyzed Selective Oxidation in Liquid Phase
T. Ishida
Kick-Off Workshop for Research Center for Gold Chemistry, Tokyo Metropolitan University, 2014.05.15 - Novel Catalysis by Supported Gold Nanoparticles
M. Haruta
Nanqiang Lecture, Xiamen University, P. R. China, 2015.04.20 - Simple Chemistry Catalyzed by Gold Nanoparticles
M. Haruta
The 7th International Conference on Gold Science, Technology and its Applications (GOLD2015), Cardiff City Hall, UK, 2015.07.26 (Plenary) - Unique Catalysis of Gold Nanoparticles
M. Haruta
Kagoshima University Project Gold 2015 Symposium, Kagoshima University, 2016.02.12 - What I Had Learned at Nagoya Gakuin: Dreams Expanded to the World
M. Haruta
Seminar of Nagoya Gakuin Mumei-kai, Aichi, Japan, 2013.03.15 - A Modern Alchemy: Gold Nanotechnology
M. Haruta
NBC Meshtec Inc. Annual Meeting, NBC Meshtec Inc., Tokyo, Japan, 2013.03.14 - Fascinated by Gold: Randomness and Necessity
M. Haruta
“Career Guidance Day” The 1st Part, Career Guidance, Nagoya Senior High School, Aichi, Japan, 2012.12.15 - Researchers are Dreamers
M. Haruta
“Career Guidance Day” The 2nd Part, Individual Course, Nagoya Senior High School, Aichi, Japan, 2012.12.15 - Gold Catalysis and Applications to Green Chemistry
M. Haruta
he Catalysis Society of Japan (CATSJ), Lecture Meeting in Tsukuba area, The National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba Central 1, Ibaraki, Japan, 2012.12.14 - Nanotechnology which Expand Applications of Gold — Great Potential of Gold —
M. Haruta
WGC 1st Gold Academy, Mandarin Oriental Tokyo, Tokyo, Japan, 2012.11.29 - Preparation Methods and Catalytic Properties of Gold Nanoparticles
M. Haruta
17th Symposium “Synthetic Processes for Noble Metal Films and Particles”, Nippon Institute of Technology Kanda Campus, Tokyo, Japan, 2012.11.21 - Novel Catalysis by Supported Gold Clusters: from Nanoparticles to Clusters
M. Haruta
9th Catalysis Seminar by Sagami Chemical Research Institute, Tosoh Tokyo Research Center, Kanagawa, Japan, 2012.11.16 - Causes and Counter Measures for the Deactivation of Gold Catalysts Active at Ambient Temperature
M. Haruta
6th Seminar of Catalyst Deactivation, Campus Innovation Center Tokyo, Tokyo, Japan, 2012.11.15 - Highly Selective Reaction Catalyzed by Supported Gold Clusters Composed of Defined Number of Atoms
M. Haruta
JST New Technology Presentation Meeting, Ichigaya, Tokyo, Japan, 2012.07.06 - Generation of the Novel Catalysis by Gold Clusters
M. Haruta
The Memorial Symposium on the Establishment of Center for Exploration of New Inorganic Materials, Tohoku University, Miyagi, Japan, 2012.07.03 - Novel Catalysis by Supported Gold Clusters
M. Haruta
1st JACI/GSC Symposium, Bellesalle Kanda, Tokyo, Japan, 2012.06.13 - Aerobic oxidation of sulfides to sulfoxides over manganese oxides prepared by different methods
A. Taketoshi, M. Haruta
Asian International Symposium on the 92nd Chemical Society of Japan (CSJ) Annual Meeting, Keio University, Japan, 2012.03.27 - Green Chemistry by Gold Cluster Catalysts
M. Haruta
Catalyst Club, Osaka, Japan, 2012.01.27 - The Role of Water and Perimeter in Catalytic Activity of Gold Nanoparticles
M. Haruta
JST-CREST Meeting, Ichigaya, Japan, 2012.01.25 - Mystery of Catalysts
M. Haruta
Community Salon of Education-Industry, Chuo Universiy, Japan, 2011.12.09 - Green Chemistry by Gold Cluster Catalysts
M. Haruta
The Meeting of JST-CREST (Basic technology of nano-interface), Tokyo, Japan, 2011.10.25 - Application and Interesting Catalytic Activity of Gold Nanoparticles
M. Haruta
Seminar of Catalytic Technology, Osaka University, Japan, 2011.10.21 - The Role of Water and Perimeter in Catalytic Activity of Gold Nanoparticles
M. Haruta
The 32nd summer meeting of the Catalysis Society of Japan, Hmamatsu, Japan, 2011.08.08 - Surface Phenomena on Solids -Adsorption and Surface Structure of Solids-
T. Takei
The 27th Basic Lecture of Modern Colloid and Interface Chemistry, Tokyo, Japan, 2011.05.19 - New Catalysis by Gold
M. Haruta
Tokyo U-Club Regular Meeting, Tokyo Metropolitan University, Akihabara, 2010.12.03 - Gold Catalysts for Ethanol Oxidation to ProduceAcetaldehyde and Acetic Acid
M. Haruta
JST New Technology Presentation Meetings, JST Hall, Tokyo, 2010.06.25 - Catalysis by Gold Nanoclusters: From Fundamentals to Industrial Applications
M. Haruta
The University of Tokyo, “Frontier Chemistry”, Tokyo, 2010.06.14 - Interests in Gold:Wide Variety of Catalytic Properties
M. Haruta
100th The Society of Graphite Compounds Meeting,Kyoto, 2010.05.20 - New Properties of Gold Clusters
M. Haruta
The Japan Society for Promotion of Science, The 141th Committee Lecture, Kyoto, 2010.05.19 - Catalysis of Gold: NanoWonderland
M. Haruta
Keio University Special Lecture, Tokyo, 2010.04.17 - Catalysis by Gold Clusters
M. Haruta
The 48th Memorial Symosium of Prof. Tamaki, Kyoto University, 2009.10.01 - Mechanism for Catalysis by Supported Gold Nanoparticles
M. Haruta
Fuel Cell Related Catalyst Division in Catalyst Society of Japan, The second symposium for New Electrode Catalysts, Kato Foundation for Promotion of Science, Nagano, 2009.10.01 - New Catalysis by Gold Clusters
M. Haruta
The 34th Annual Meeting of the Society for Atomic Collision Research, Tokyo Metropolitan University, 2009.08.01 - Catalysis by Gold for Green Chemistry
M. Haruta
Catalysis Colloquium, Sophia University, Tokyo, 2009.06.01 - Catalysis by Gold Nanoparticles for Environmentaly Benign Chemistry
T. Ishida, M. Haruta
Tokyo Metropolitan Industrial Technology Research Institute, 2009.06.01 - Physical Chemistry of Solid Surfaces and Nanoporous Materials
T. Takei
25th Fundamental Lecture of Modern Colloid and Interface Science”, Division of Colloid and Interface Science, The Chemical Society of Japan, 2009.05.01 - Deposition of Gold Nanoparticles onto Various Kinds of Support Materials
M. Haruta
TMU Research Seeds Meetings 2008, Tokyo, 2008.11.01 - Catalysis by Gold: Wonder of Nano-World
M. Haruta
The Institution of Professional Engineers Japan, Nagoya, 2008.11.01 - Deposition of Gold Nanoparticles and its Application to Catalysts
M. Haruta
Kanagawa Industial Technology Center, Kangawawa, 2008.10.01 - Air Purification by Gold Catalyst
T. Takei
Sangaku Renkei Plaza 2008, Lumieru Fuchu, 2008.10.01 - Deposition of Gold Clusters and its Application to Catalysts and Sensors
M. Haruta
The Ceramic Society of Japan, Fukuoka, 2008.09.01 - Support and Size Effect of Gold Catalysts on Selective Oxidations
M. Haruta
The 102nd Meetings on the Catalysis Society of Japan, Nagoya, 2008.09.01 - Support Effect of Ceramics for Gold Nanoparticles Catalysts
M. Haruta
JSPS, Tokyo, 2008.09.01 - Deposition of Gold Nanoparticles onto Polymer Surfaces
M. Haruta
TMU/JST New Technology Presentation Meetings, Tokyo, 2008.07.01 - Direct Deposition of Gold Nanoparticles onto Polymers and Carbons-Application to Catalysts
M. Haruta
JST New Technology Presentation Meetings, Tokyo, 2008.06.01 - Principles of Catalysis and Structures for Gold Nanoparticles
M. Haruta
The Japanese Society of Microscopy, Kyoto, 2008.05.01 - Size Effect and Catalysis of Nanoparticles
M. Haruta
The 88th Spring Meeting on The Chemical Society of Japan, Rikkyo University, 2008.03.01 - Green Sustainable Chemistry:Approaches from Solvents and Catalysts
M. Haruta
The 88th Spring Meeting on The Chemical Society of Japan, Rikkyo University, 2008.03.01 - Direct Deposition of Gold Nanoparticles onto Polymer Supports and Their Catalytic Properties
T. Ishida
The Kyushu University FR・AS Symposium, Kyushu University, 2008.03.01 - Modern Alchemy: Nanoparticulate Gold Catalysts
M. Haruta
Owari Tono Monozukuri Sangakukan Network The 4th Seminar, 2008.01.01 - Catalysis by Gold !, Lecture Series” Enjoy to know”,-Watch Research Frontiers
M. Haruta
Komaba Senior High School at Otsuka, University of Tsukuba, 2007.12.01 - Air Purification and Green Chemistry by Nanoparticulate Gold Catalysts
M. Haruta
Fiber Science and Technology Kanto Division Lecture, Tokyo Institute of Technology, 2007.12.01 - Modern Alchemy:Creation of Catalysis from Gold
M. Haruta
Nanoparticles, Special Lecture in Ritsumeikan University, Kusatsu Biwako Campus Ritsumeikan University, 2007.11.01 - Modern Alchemy: A New World Created by Gold Nanoparticles
M. Haruta
Kinki University, Faculty of Industrial Science and Technology Academic Lecture, Iizuka, 2007.11.01 - Modern Alchemy: Gold Nanoparticles and Clusters
M. Haruta
Japan Vacuum Society & Surface Science Society of Japan Seminar, Kobe University, 2007.07.01 (Plenary) - New applications of nanoparticulate gold catalysts using solid acid support
Toru Murayama
ICAT International Joint Symposium in Cardiff, 2019.01.17 - Temperature-Dependent Activation Properties for Carbon Monoxide Oxidation by Polyoxometalate-Supported Gold Nanoparticulate Catalysts
Toru Murayama*, Takuya Yoshida, Mingyue Lin, Norihito Sakaguchi, Tamao Ishida, Masatake Haruta
The 8th Tokyo Conference on Advanced Catalytic Science and Technology (TOCAT8), 2018.08.05 - Preparation and Catalytic Porperties of Supported Gold Nanoparticles and Clusters
Tamao Ishida
Singapore-Japan Bilateral Meeting on Functional Materials Chemistry, 2018.04.26 - Heterogeneous Gold Nanoparticles as Soft Lewis Acid Catalysts for Transfer Vinylation of Carboxylic Acids
Tamao Ishida
Intenational Symposium on Catalysis and Fine Chemicals (C&FC) 2018, 2018.12.13 - DNA nanoplate-based functional microdroplets furnished with ion-channel function
Daisuke Ishikawa
ICPAC Langkawi 2018 (International Congress on Pure & Applied Chemistry), 2018.10.31
Abstracts of Selected Articles
Books, Reviews, Accounts
T. Takei, T. Akita, I. Nakamura, T. Fujitani, M. Okumura, K. Okazaki, J. Huang, T. Ishida, M. Haruta
Advances in Catalysis, 55, B.C. Gates, F.C. Jentoft ed., Elsevier, Chapter 1, 1-124 (2012)
[Web Page]External Link

This chapter is a review of recent advances in heterogeneous catalysis by gold, focusing on the advances in the latest 10 years; Preparation of Supported Gold Catalysts, Fine Structures of Supported Gold Catalysts, Surface Science of CO Oxidation Catalyzed by Gold, Theoretical Interpretations and Predictions of Catalysis by Gold, Catalysis by Gold with Reactants in the Gas Phase, Catalysis by Gold with Reactants in the Liquid Phase.
M. Haruta
Faraday Discuss., 152, 11-32 (2011)
[Web Page]External Link

This review was compiled based on the Introductory Talk of Faraday Discussion 152: Gold (at Cardiff University, on July 2011).
Gold can be deposited as nanoparticles (NPs) of 2 to 5 nm in diameter on a variety of materials such as metal oxides and carbides, carbons, organic polymers and exhibits surprisingly high catalytic activities for many reactions in both gas and liquid phases. The mechanisms for the genesis of catalysis by gold NPs is discussed based on real powder catalysts and model single crystal catalysts for two simple reactions, low-temperature oxidation of CO in which gold NPs catalysts are exceptionally active and for dihydrogen dissociation in which gold NPs catalysts are still poorly active. For both the two reactions, it has been revealed that reactions take place at perimeter interfaces around gold NPs.
Original Papers
H. Yoshida, Y. Kuwauchi, J. R. Jinschek, K. Sun, S. Tanaka. M. Kohyama, S.Shimada, M. Haruta, S. Takeda
Science, 335, 317-319 (2012)
[Web Page]External Link
Understanding how molecules can restructure the surfaces of heterogeneous catalysts under reaction conditions requires methods that can visualize atoms in real space and time. We applied a newly developed aberration-corrected environmental transmission electron microscopy to show that adsorbed carbon monoxide (CO) molecules caused the {100} facets of a gold nanoparticle to reconstruct during CO oxidation at room temperature. The CO molecules adsorbed at the on-top sites of gold atoms in the reconstructed surface, and the energetic favorability of this reconstructed structure was confirmed by ab initio calculations and image simulations. This atomic-scale visualizing method can be applied to help elucidate reaction mechanisms in heterogeneous catalysis.
X. Xie, Y. Li, Z.-Q. Liu, M. Haruta, W. Shen
Nature, 458, 746-749 (2009)
[Web Page]External Link
The development of active and stable catalysts without noble metals for low-temperature CO oxidation under an ambient atmosphere remains a significant challenge. Here we report that tricobalt tetraoxide nanorods not only catalyse CO oxidation at temperatures as low as –77 °C but also remain stable in a moist stream of normal feed gas. High-resolution transmission electron microscopy demonstrates that the Co3O4 nanorods predominantly expose their {110} planes, favouring the presence of active Co3+ species at the surface. Kinetic analyses reveal that the turnover frequency associated with individual Co3+ sites on the nanorods is similar to that of the conventional nanoparticles of this material, indicating that the significantly higher reaction rate that we have obtained with a nanorod morphology is probably due to the surface richness of active Co3+ sites. These results show the importance of morphology control in the preparation of base transition-metal oxides as highly efficient oxidation catalysts.
J. Huang, T. Akita, J. Faye, T. Fujitani, T. Takei, M. Haruta
Angew. Chem. Int. Ed., 48, 7862-7866 (2009) marked as “Hot Paper”
[Web Page]External Link
Size matters: Gold clusters (<2.0 nm), but not gold nanoparticles, deposited on alkali-treated titanosilicalite-1 enable O2 and H2O to react to give hydroperoxides (-OOH). This species transfers to neighboring Ti sites to form Ti-OOH, which is capable of propene epoxidation with molecular oxygen alone to give propene epoxide (PO).
T. Ishida, M. Nagaoka, T. Akita, M. Haruta
Chem. Eur. J., 14, 8456-8460 (2008)
[Web Page]External Link
Gold clusters were deposited in a narrow size distribution on porous coordination polymers (PCPs) by solid grinding with volatile dimethyl AuIII acetylactonate. The mean diameter could be minimized down to 1.5 nm for Al-containing PCPs. Gold clusters on PCPs showed noticeably high catalytic activity in the aerobic oxidation of alcohols. Product selectivity was tunable by the selection of PCP supports in benzyl alcohol oxidation.
M. Daté, M. Okumura, S. Tsubota, M. Haruta
Angew. Chem. Int. Ed., 43, 2129-2132 (2004) marked as “Very Important Paper”
[Web Page]External Link
Supported gold nanoparticles exhibit high catalytic activity not only at low temperatures but also under the presence of moisture. The effect of moisture on CO oxidation over Au/TiO2, Au/Al2O3, and Au/SiO2 was studied at 273 K. It was found that the catalytic activities are enhanced by moisture by up to two orders of magnitude, and that the moisture effect depends on the type of oxide support.
M. Haruta, S. Tsubota, T. Kobayashi, H. Kageyama, M. J. Genet, B. Delmon
J. Catal., 144, 175-192 (1993)
[Web Page]External Link
Gold can be highly dispersed on a variety of metal oxides by coprecipitation and deposition-precipitation followed by calcination in air. Such supported gold differs in catalytic nature from unsupported gold particles and exhibits high catalytic activities for low-temperature oxidation of CO. In the temperature range of −10 to 65°C, the activation energies for CO oxidation were 8.2 kcal/mol (Au/TiO2), 8.4 kcal/mol (Au/α-Fe2O3), and 3.9 kcal/mol (Au/Co3O4). The rate of CO oxidation is zero order with respect to CO for the three catalysts, and 0.2-0.3 for Au/TiO2 and Au/Co3O4 and zero order for Au/α-Fe2O3 with respect to O2. By taking into consideration TPD and FT-IR data, a mechanism is proposed in which CO adsorbed on gold particles migrates toward the perimeter on support oxides and there it reacts with adsorbed oxygen to form bidentate carbonate species. The decomposition of the carbonate intermediate is considered to be rate-determining.
M. Haruta, T. Kobayashi, H. Sano, N. Yamada
Chem. Lett., 405-408 (1987)
[Web Page]External Link
A variety of gold catalysts can be used to catalyze the oxidation of carbon monoxide at temperatures as low as −70 °C and are stable in a moistened gas atmosphere. The novel catalysts, prepared by coprecipitation, are composed of ultra-fine gold particles and one of the oxides of 3d transition metals of group VIII, namely, Fe, Co, and Ni.